Analysis of toxic effects and nutrient stress in aquatic ecosystems

Bontje, D. 2010. Analysis of toxic effects and nutrient stress in aquatic ecosystems.
PHD Thesis Vrije Universiteit, Amsterdam

Abstract

Chapter 2

We study the effects of toxicants on the functioning of a phototrophic unicellular organism (an algae) in a simple aquatic microcosm by applying a parameter-sparse model. The model allows us to study the interaction between ecological and toxicological effects. Nutrient stress and toxicant stress, together or alone, can cause extinction of the algal population. The modelled algae consume dissolved inorganic nitrogen (DIN) under surplus light and use it for growth and maintenance. Dead algal biomass is mineralized by bacterial activity, leading to nutrient recycling. The ecological model is coupled with a toxicity-module that describes the dependency of the algal growth and death rate on the toxicant concentration. Model parameter fitting is performed on experimental data from Liebig et al. (2008). These experiments were especially designed to include nutrient limitation, nutrient recycling and long-term exposure to toxicants. The flagellate species Cryptomonas sp. was exposed to the herbicide prometryn and insecticide methyl parathion in semiclosed Erlenmeyers. Given the total limiting amount of nitrogen in the system, the estimated toxicant concentration at which a long-term steady population of algae goes extinct will be derived. We intend to use the results of this study to investigate the effects of ecological (environmental) and toxicological stresses on more realistic ecosystem structure and functioning.

Chapter 3

Since Rosenzweig showed the destabilisation of exploited ecosystems, the so called Paradox of enrichment, several mechanisms have been proposed to resolve this paradox. In this paper we will show that a feeding threshold in the functional response for predators feeding on a prey population stabilizes the system and that there exists a minimum threshold value above which the predator-prey system is unconditionally stable with respect to enrichment. Two models are analysed, the first being the classical Rosenzweig- MacArthur (RM) model with an adapted Holling type-II functional response to include a feeding threshold. This mathematical model can be studied using analytical tools, which gives insight into the mathematical properties of the two dimensional ode system and reveals underlying stabilisation mechanisms. The second model is a mass-balance (MB) model for a predator-prey-nutrient system with complete recycling of the nutrient in a closed environment. In this model a feeding threshold is also taken into account for the predatorprey trophic interaction. Numerical bifurcation analysis is performed on both models. Analysis results are compared between models and are discussed in relation to the analytical analysis of the classical RM model. Experimental data from the literature of a closed system with ciliates, algae and a limiting nutrient are used to estimate parameters for the MB model. This microbial system forms the bottom trophic levels of aquatic ecosystems and therefore a complete overview of its dynamics is essential for understanding aquatic ecosystem dynamics.

Chapter 4

In Chapter 2 we studied the effects of toxicants on the functioning of phototrophic unicellulars (algae) in a simple aquatic microcosm with a parameter-sparse model. Now we extend this model to include algivorous ciliates. The modelled algae consume dissolved inorganic nitrogen (DIN) under surplus light and use it for growth and maintenance. The ciliates feed on the algae for growth and maintenance. Dead bacteria, feeding waste-products and dead ciliates add to a detritus pool. Detritus is mineralized by bacterial activity, leading to nutrient recycling. The ecological model is coupled with a toxicity-module that describes the dependency of each species biological rates on the toxicant concentration. Model parameter fitting is performed on experimental data from Liebig et al. (2008). The flagellate species Cryp- tomonas sp. was exposed to the herbicide prometryn and insecticide methyl parathion in semi-closed Erlenmeyers while being preyed upon by either the ciliate Urotricha furcata or Coleps spetai with the autotrophic endosymbiont Chlorella sp.. Effects of methyl parathion on Urotricha furcata are directly as an increased death rate and indirectly via a reduced prey availability as algal growth was reduced.Coleps spetai with its endosymbiont with chlorophyll was found to be insensitive to prometryn and only su ered from food shortage.

Chapter 5

In this Chapter we study the sublethal effect of toxicants on the functioning (biomass production, nutrient recycling) and structure (species composition and complexity) of a simple aquatic ecosystem in a well-mixed environment (chemostat reactor). The modelled ecosystem consists of a nutrient consumed by a prey (e.g. bacteria, alga) which, in turn, is consumed by a predator (e.g. ciliates, daphnia) population. The dynamic behaviour of this ecosystem is described by a set of ordinary differential equations (odes): one for the nutrient and one for each population. The system is stressed by a toxicant dissolved in the in-flowing water. The transport of the toxicant is modelled using a mass balance formulation leading to an ode. Bio-accumulation in the prey and predator populations is via uptake from the water phase, in case of the predator also via consumption of contaminated prey. Mathematically this process is described by a one-compartment model for the kinetics of the toxicant: uptake (from water and food) and elimination. The toxicant affects the development of individuals which make up populations. In the model the physiological parameters depend on the internal concentration of the toxicant in individuals. Examples of physiological parameters are cost for growth, assimilation e ciency and maintenance rate. In this Chapter we use bifurcation theory. In this way the parameter space is divided into regions with qualitatively different asymptotic dynamic behaviour of the system. As logical choice for bifurcation parameters are the strength of the forcing on the system determined by the input rate of nutrient and toxicant. Our analysis reveals that the relationship between the population biomass and the amount of toxicant in the reactor is of paramount importance. The dynamic behaviour of the stressed ecosystem can be much more complicated than that of the unstressed system. For instance the nutrient-prey-contaminant system can show bi-stability and oscillatory dynamics. Due to the toxic effects a total collapse of the nutrient-prey-predator-contaminant system can occur after invasion of a predator, in which case both prey and predator population go extinct.

Chapter 6

The dynamical behaviour is analysed of a stressed (nutrient and toxic stress) aquatic ecosystem (for instance a stretch of river) consisting of nutrients, biotic pelagic and benthic communities and detritus pools in the abiotic water body and on the sediment. We analyse the downstream river reach adjacent to the point of emission of the toxicant. The toxicant is taken up by the organisms and can affect different chemical-biotic processes in the populations thereby changing their biological functioning (assimilation, growth, maintenance, reproduction, survival). These effects on the behaviour of the populations induce effects on the ecosystem structure and functioning e.g. extinction or invasion of species. The dynamic behaviour of all populations and toxicant concentration in the water, sediment, detritus and in the organisms that built up the populations, is mathematically described by a set of ordinary differential equations (odes), taking intra- and interspecific interactions and transport from and to adjacent river reaches into account. The set of equations describing the long-term dynamic behaviour of the ecosystem is analysed using bifurcation theory to find and continue parameter value combinations where a population goes extinct or where the ecosystem shows oscillatory behaviour. As bifurcation parameters we will take the nutrient input (enrichment) and concentration of the toxicant in the inflow (toxic exposure). We calculate the boundaries of the range of the parameters that describe the forcing and loading where the system behaves similarly, that is the long-term dynamics is qualitatively the same (equilibrium, oscillatory or chaotic behaviour) [and areas where the quantities are the same]. In this way we obtain levels of toxic loading where the abundances of all populations are the same as in the control case. We will also calculate the boundary of regimes of toxic stress levels that do not lead to a change in the composition of the ecosystem and therefore its structure, but where population abundances and internal toxicant concentrations may change quantitatively. An integrated approach is used whereby the effects of toxicological (toxic exposure), ecological (feeding, predation, competition) and environmental stressors (dilution rate) are analysed simultaneously. Due to feed-back mechanisms such as indirect effects, between toxic exposure and physical and ecological processes even low toxic stress can lead to drastic changes in the ecosystem functioning and structure.

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